7月12日TimothyR.Cook副教授:Coordination-Driven Self-Assembly of Photo-and Redox-Active Metallacycles and Cages

发布日期:2015-07-07发布者:李艳艳浏览次数:122

报告题目:Coordination-Driven Self-Assembly of Photo-and Redox-Active Metallacycles and Cages

报告人:TimothyR.Cook副教授

报告时间:2015.7.12星期日上午10:00

报告地点:中北校区化学馆A305

报告人简介:

TimothyR.Cook副教授⏺,纽约州立大学布法罗分校化学系

2001-2005年,波士顿大学🐦,学士;2005-2010年,麻省理工天美🙎🏿‍♀️,博士;

2010-2014年,犹他大学👨🏼‍🍳,博士后👩‍👦‍👦、助理教授;

2014年-至今纽约州立大学布法罗分校副教授

报告内容摘要😭:

The formation of structurally complex metal-organic polygons, polyhedra, and prisms (MOPs) is greatly facilitated by self-assembly methods which furnish them in single, one-pot reactions. An ever-growing library of organic ligands (donors) and metal/organometallic complexes with substitutionally labile coordination sites (acceptors) serves as the basis for a suite of metallacycles and cages characterized by their well-defined internal cavities and predictable topologies. These approaches are mirrored in efforts to obtain electrochemically active materials: redox-active moieties may be coupled to the periphery of a given MOP. Alternatively, the metal nodes may prove competent forreversible redox chemistry, motivating applications in catalysis and charge carrying devices.

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